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SOLVED:The longer the chain in polymer A, the bigger the sphere it coils into. There isn't much problem comparing samples of polymer A to each other, provided we have some way of calibrating sphere size to chain length. However, polymer B appears to be more tightly coiled than A. A relatively small sphere could pack a lot more chain. We would have to be cautious about comparing the sphere size of B to that of A and drawing any conclusions about chain length or molecular weight.
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